Efficient Access to Inverse Bicontinuous Mesophases via Polymerization-Induced Cooperative Assembly
نویسندگان
چکیده
منابع مشابه
On the Swelling of Bicontinuous Lyotropic Mesophases
The swelling of sponge-like bicontinuous mesophases of bilayers of surfactant (or lipid) in water as a function of dilution is analyzed. Analytic formulae for the swelling are derived assuming ii) constant aggregate thickness and (it) fixed surface area per surfactant molecule at an imaginary surface located within the bilayer. Approximate swelling laws are derived for bicontinuous films and co...
متن کاملKinetics and mechanism of the interconversion of inverse bicontinuous cubic mesophases.
This paper describes time-resolved x-ray diffraction data monitoring the transformation of one inverse bicontinuous cubic mesophase into another, in a hydrated lipid system. The first section of the paper describes a mechanism for the transformation that conserves the topology of the bilayer, based on the work of Charvolin and Sadoc, Fogden and Hyde, and Benedicto and O'Brien in this area. We s...
متن کاملPolymerization-Induced Self-Assembly of Block Copolymer Nano-objects via RAFT Aqueous Dispersion Polymerization
In this Perspective, we discuss the recent development of polymerization-induced self-assembly mediated by reversible addition-fragmentation chain transfer (RAFT) aqueous dispersion polymerization. This approach has quickly become a powerful and versatile technique for the synthesis of a wide range of bespoke organic diblock copolymer nano-objects of controllable size, morphology, and surface f...
متن کاملPrecision Aliphatic Polyesters via Segmer Assembly Polymerization.
Precise structure-property relation of a biodegradable polymer (e.g., aliphatic polyester) is anticipated only if monomer units and chiral centers are arranged in a defined primary sequence as a biomacromolecule. An emerging synthetic methodology, namely segmer assembly polymerization (SAP), is introduced in this paper to reveal the latest progress in polyester synthesis. Almost any periodic po...
متن کاملOne-pot synthesis of nanomaterials via RAFT polymerization induced self-assembly and morphology transition.
A simple and facile strategy has been developed for synthesis of nanomaterials via polymerization in high concentration; multiple morphologies can be created and tuned just by variation of the feed ratio and reaction conditions.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: CCS Chemistry
سال: 2020
ISSN: 2096-5745
DOI: 10.31635/ccschem.020.202000407